6-脫氧卷線孢菌素

6-脫氧卷線孢菌素
	IUPAC名; (5S,7S)-5,7,9,10-Tetrahydroxy-2-methoxy-7-methyl-5,6,7,8-tetrahydroanthracene-1,4-dione
識別
CAS號	97400-69-6
PubChem	11209399
ChemSpider	9384461
SMILES	C[C@]1(C[C@@H](C2=C(C3=C(C(=C2C1)O)C(=O)C(=CC3=O)OC)O)O)O;
InChI	1/C16H16O7/c1-16(22)4-6-10(8(18)5-16)15(21)11-7(17)3-9(23-2)14(20)12(11)13(6)19/h3,8,18-19,21-22H,4-5H2,1-2H3/t8-,16-/m0/s1;
InChIKey	WWTHHBSODPGTAK-PWJLMRLQBI
性質
化學式	C16H16O7
摩爾質量	320.29 g·mol−1
外觀	暗紅色針狀晶體
熔點	193~195 °C（+）; 194~198 °C（±）
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

6-脫氧卷線孢菌素（(5S,7S)-5,6,7,8-四氫-5,7,9,10-四羥基-2-甲氧基-7-甲基-1,4-蒽醌）是一種有機化合物，化學式為C₁₆H₁₆O₇，其英文名「austrocortirubin」源自於澳大利亞的絲膜菌屬（Cortinarius）的毒蕈。^[3]它可以2,5,8-三羥基-1,4-萘醌（維基數據所列：Q82903034）的縮醛為原料合成得到。^[2]

參考文獻[編輯]

^ ^1.0 ^1.1 Melvyn Gill, Albin F. Smrdel, Richard J. Strauch and Michael J. Begley. Pigments of fungi. Part 12. Structure and absolute stereochemistry of antibiotic tetrahydroanthraquinones from the fungus Dermocybe splendida Horak. X-Ray structure determination of austrocortirubin phenylboronate and austrocortilutein acetonide. J. Chem. Soc., Perkin Trans. 1, 1990, 1583-1592. doi:10.1039/P19900001583.
^ ^2.0 ^2.1 Burns, CJ; Gill, M (1991). Pigments of Fungi. XXII. Synthesis of (±)-Austrocortirubin and Related Tetrahydroanthraquinones. Australian Journal of Chemistry, 44(10), 1447–1458. doi:10.1071/CH9911447
^ Melvyn Gill; Richard J. Strauch (1985). New tetrahydroanthraquinones from the genus Cortinarius. Tetrahedron Letters, 26 (21), 2593–2596. doi:10.1016/s0040-4039(00)98845-2.

這是一篇關於有機化合物的小作品。您可以透過編輯或修訂擴充其內容。

[Gill-1] 1.0 ^1.1 Melvyn Gill, Albin F. Smrdel, Richard J. Strauch and Michael J. Begley. Pigments of fungi. Part 12. Structure and absolute stereochemistry of antibiotic tetrahydroanthraquinones from the fungus Dermocybe splendida Horak. X-Ray structure determination of austrocortirubin phenylboronate and austrocortilutein acetonide. J. Chem. Soc., Perkin Trans. 1, 1990, 1583-1592. doi:10.1039/P19900001583.

[Burns-2] 2.0 ^2.1 Burns, CJ; Gill, M (1991). Pigments of Fungi. XXII. Synthesis of (±)-Austrocortirubin and Related Tetrahydroanthraquinones. Australian Journal of Chemistry, 44(10), 1447–1458. doi:10.1071/CH9911447

[3] Melvyn Gill; Richard J. Strauch (1985). New tetrahydroanthraquinones from the genus Cortinarius. Tetrahedron Letters, 26 (21), 2593–2596. doi:10.1016/s0040-4039(00)98845-2.

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