6-脱氧卷线孢菌素

6-脱氧卷线孢菌素
	IUPAC名; (5S,7S)-5,7,9,10-Tetrahydroxy-2-methoxy-7-methyl-5,6,7,8-tetrahydroanthracene-1,4-dione
识别
CAS号	97400-69-6
PubChem	11209399
ChemSpider	9384461
SMILES	C[C@]1(C[C@@H](C2=C(C3=C(C(=C2C1)O)C(=O)C(=CC3=O)OC)O)O)O;
InChI	1/C16H16O7/c1-16(22)4-6-10(8(18)5-16)15(21)11-7(17)3-9(23-2)14(20)12(11)13(6)19/h3,8,18-19,21-22H,4-5H2,1-2H3/t8-,16-/m0/s1;
InChIKey	WWTHHBSODPGTAK-PWJLMRLQBI
性质
化学式	C16H16O7
摩尔质量	320.29 g·mol−1
外观	暗红色针状晶体
熔点	193~195 °C（+）; 194~198 °C（±）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

6-脱氧卷线孢菌素（(5S,7S)-5,6,7,8-四氢-5,7,9,10-四羟基-2-甲氧基-7-甲基-1,4-蒽醌）是一种有机化合物，化学式为C₁₆H₁₆O₇，其英文名“austrocortirubin”源自于澳大利亚的丝膜菌属（Cortinarius）的毒蕈。^[3]它可以2,5,8-三羟基-1,4-萘醌（維基數據所列：Q82903034）的缩醛为原料合成得到。^[2]

参考文献[编辑]

^ ^1.0 ^1.1 Melvyn Gill, Albin F. Smrdel, Richard J. Strauch and Michael J. Begley. Pigments of fungi. Part 12. Structure and absolute stereochemistry of antibiotic tetrahydroanthraquinones from the fungus Dermocybe splendida Horak. X-Ray structure determination of austrocortirubin phenylboronate and austrocortilutein acetonide. J. Chem. Soc., Perkin Trans. 1, 1990, 1583-1592. doi:10.1039/P19900001583.
^ ^2.0 ^2.1 Burns, CJ; Gill, M (1991). Pigments of Fungi. XXII. Synthesis of (±)-Austrocortirubin and Related Tetrahydroanthraquinones. Australian Journal of Chemistry, 44(10), 1447–1458. doi:10.1071/CH9911447
^ Melvyn Gill; Richard J. Strauch (1985). New tetrahydroanthraquinones from the genus Cortinarius. Tetrahedron Letters, 26 (21), 2593–2596. doi:10.1016/s0040-4039(00)98845-2.

这是一篇关于有机化合物的小作品。您可以通过编辑或修订扩充其内容。

[Gill-1] 1.0 ^1.1 Melvyn Gill, Albin F. Smrdel, Richard J. Strauch and Michael J. Begley. Pigments of fungi. Part 12. Structure and absolute stereochemistry of antibiotic tetrahydroanthraquinones from the fungus Dermocybe splendida Horak. X-Ray structure determination of austrocortirubin phenylboronate and austrocortilutein acetonide. J. Chem. Soc., Perkin Trans. 1, 1990, 1583-1592. doi:10.1039/P19900001583.

[Burns-2] 2.0 ^2.1 Burns, CJ; Gill, M (1991). Pigments of Fungi. XXII. Synthesis of (±)-Austrocortirubin and Related Tetrahydroanthraquinones. Australian Journal of Chemistry, 44(10), 1447–1458. doi:10.1071/CH9911447

[3] Melvyn Gill; Richard J. Strauch (1985). New tetrahydroanthraquinones from the genus Cortinarius. Tetrahedron Letters, 26 (21), 2593–2596. doi:10.1016/s0040-4039(00)98845-2.

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