4-氯叔丁苯
| 4-氯叔丁苯 | |
|---|---|
| |
| 識別 | |
| CAS號 | 3972-56-3 
|
| SMILES |
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| 性質 | |
| 化學式 | C10H13Cl |
| 摩爾質量 | 168.66 g·mol−1 |
| 熔點 | 22.5 °C[1] |
| 沸點 | 210-212 °C[2] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
4-氯叔丁苯是一種有機氯化合物，化學式為C10H13Cl。它可由氯苯和2-甲基-2-丁烯在氯化鋁催化下反應得到。[2]
在叔丁醇鉀的存在下和鈀配合物的催化下，它可以發生脫氯反應，得到叔丁苯。[3]它和硝酸、硫酸反應，可以得到4-叔丁基-2-硝基氯苯。[4]
參考文獻
[編輯]- ^ Leon M. Stock and Herbert C. Brown. Relative Rates and Isomer Distributions in the Halogenation of t-Butylbenzene and Some of Its Derivatives. Partial Rate Factors for Non-catalytic Bromination and Chlorination in Acetic Acid. J. Am. Chem. Soc. 1959. 81 (21). doi:10.1021/ja01530a024
- ^ 2.0 2.1 B. S. Friedman and Fred L. Morritz. t-Butylation of Aromatics with Isoamylene. J. Am. Chem. Soc. 1956. 78 (14). doi:10.1021/ja01595a046.
- ^ Angela Burhenn, Roberta Bavaro and Viktoria H. Gessner. Pd-catalysed hydrodehalogenation of aryl chlorides: a mild method for deuteration and detoxification. Catal. Sci. Technol., 2023,13, 3545-3550. doi:10.1039/D3CY00432E.
- ^ Yvonne Grell, Nemrud Demirel, Klaus Harms, and Eric Meggers. Chiral Bis(oxazoline) Ligands as C2-Symmetric Chiral Auxiliaries for the Synthesis of Enantiomerically Pure Bis-Cyclometalated Rhodium(III) Complexes. Organometallics 2019, 38, 19, 3852–3859. doi:10.1021/acs.organomet.9b00533.