碳化十五羰基五釕

碳化十五羰基五釕
別名	μ5-碳化十五羰基五釕
識別
CAS號	51205-07-3
性質
化學式	C16O15Ru5
摩爾質量	937.52 g·mol−1
外觀	紅色晶體
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

碳化十五羰基五釕是一種有機釕化合物（英語：Organoruthenium chemistry），化學式為Ru₅C(CO)₁₅。它可由Ru₆C(CO)₁₇和一氧化碳在70 °C、80 atm反應製得。它可作為電子對的接受體參與反應，如和一分子或二分子乙腈形成加合物；和碘反應得到Ru₅C(CO)₁₅I₂；和三苯基膦反應得到Ru₅C(CO)₁₅PPh₃。^[2]它在庚烷中加壓、加熱分解，得到Ru₆C(CO)₁₇。^[1]它可以活化甲醯基的C-H鍵。^[3]

參考文獻[編輯]

^ ^1.0 ^1.1 Brian F. G. Johnson, Jack Lewis, J. Nicola Nicholls, José Puga, Paul R. Raithby, Maria J. Rosales, Mary McPartlin, William Clegg. The synthesis of [Ru 5 C(CO) 15 ] by the carbonylation of [Ru 6 C(CO) 17 ] and the reactions of the pentanuclear cluster with a variety of small molecules: the X-ray structure analyses of [Ru 5 C(CO) 15 ], [Ru 5 C(CO) 15 (MeCN)], [Ru 5 C(CO) 14 (PPh 3 )], [Ru 5 C(CO) 13 (PPh 3 ) 2 ], and [Ru 5 (µ-H) 2 C(CO) 12 {Ph 2 P(CH 2 ) 2 PPh 2 }]. J. Chem. Soc., Dalton Trans. 1983, (2): 277–290 [2020-12-08]. ISSN 0300-9246. doi:10.1039/DT9830000277 （英語）.
^ David H. Farrar, Peter F. Jackson, Brian F. G. Johnson, Jack Lewis, J. Nicola Nicholls, Mary McPartlin. A high-yield synthesis of Ru5C(CO)15 by the carbonylation of Ru6C(CO)17; the X-ray structure analyses of Ru5C(CO)15 and Ru5C(CO)14PPh3. Journal of the Chemical Society, Chemical Communications. 1981, (9): 415 [2020-12-08]. ISSN 0022-4936. doi:10.1039/c39810000415 （英語）.
^ Richard D. Adams, Humaiara Akter, Jonathan D. Tedder. CH activations in aldehydes in reactions with Ru5(μ5-C)(CO)15. Journal of Organometallic Chemistry. 2018-09, 871: 159–166 [2020-12-08]. doi:10.1016/j.jorganchem.2018.07.017. （原始內容存檔於2020-02-16）（英語）.

[Johnson-1] 1.0 ^1.1 Brian F. G. Johnson, Jack Lewis, J. Nicola Nicholls, José Puga, Paul R. Raithby, Maria J. Rosales, Mary McPartlin, William Clegg. The synthesis of [Ru 5 C(CO) 15 ] by the carbonylation of [Ru 6 C(CO) 17 ] and the reactions of the pentanuclear cluster with a variety of small molecules: the X-ray structure analyses of [Ru 5 C(CO) 15 ], [Ru 5 C(CO) 15 (MeCN)], [Ru 5 C(CO) 14 (PPh 3 )], [Ru 5 C(CO) 13 (PPh 3 ) 2 ], and [Ru 5 (µ-H) 2 C(CO) 12 {Ph 2 P(CH 2 ) 2 PPh 2 }]. J. Chem. Soc., Dalton Trans. 1983, (2): 277–290 [2020-12-08]. ISSN 0300-9246. doi:10.1039/DT9830000277 （英語）.

[2] David H. Farrar, Peter F. Jackson, Brian F. G. Johnson, Jack Lewis, J. Nicola Nicholls, Mary McPartlin. A high-yield synthesis of Ru5C(CO)15 by the carbonylation of Ru6C(CO)17; the X-ray structure analyses of Ru5C(CO)15 and Ru5C(CO)14PPh3. Journal of the Chemical Society, Chemical Communications. 1981, (9): 415 [2020-12-08]. ISSN 0022-4936. doi:10.1039/c39810000415 （英語）.

[3] Richard D. Adams, Humaiara Akter, Jonathan D. Tedder. CH activations in aldehydes in reactions with Ru5(μ5-C)(CO)15. Journal of Organometallic Chemistry. 2018-09, 871: 159–166 [2020-12-08]. doi:10.1016/j.jorganchem.2018.07.017. （原始內容存檔於2020-02-16）（英語）.

[1]

[2]

[3]