吡啶-2,6-二甲醛
| 吡啶-2,6-二甲醛 | |
|---|---|
| |
| 别名 | 2,6-二甲酰基吡啶 |
| 识别 | |
| CAS号 | 5431-44-7 
|
| PubChem | 79485 |
| ChemSpider | 71798 |
| SMILES |
|
| EINECS | 226-589-6 |
| 性质 | |
| 化学式 | C7H5NO2 |
| 摩尔质量 | 135.12 g·mol−1 |
| 外观 | 白色固体 |
| 熔点 | 124 °C（397 K） |
| 危险性 | |
GHS危险性符号
| |
| GHS提示词 | Warning |
| H-术语 | H315, H319, H335 |
| P-术语 | P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
吡啶-2,6-二甲醛是一种有机化合物，化学式为C5H3N(CHO)2，是吡啶二甲醛的同分异构体之一。它可由2,6-二甲基吡啶的氧化反应制得。[1]它可以和胺缩合，得到二亚氨基吡啶配体。[2][3]它可以被硼氢化钠还原，得到吡啶-2,6-二甲醇。[4]
参考文献
[编辑]- ^ Forni, Lucio; Casalone, Gianluigi. Vapour Phase Oxidation of 2,6-Lutidine to 2,6-Pyridinedicarboxaldehyde. III: Kinetic Study. Applied Catalysis. 1987, 34: 317–328. doi:10.1016/S0166-9834(00)82465-3.
- ^ Britovsek, George J. P.; Bruce, Michael; Gibson, Vernon C.; Kimberley, Brian S.; Maddox, Peter J.; Mastroianni, Sergio; McTavish, Stuart J.; Redshaw, Carl; Solan, Gregory A.; Strömberg, Staffan; White, Andrew J. P.; Williams, David J. Iron and Cobalt Ethylene Polymerization Catalysts Bearing 2,6-Bis(Imino)Pyridyl Ligands: Synthesis, Structures, and Polymerization Studies. Journal of the American Chemical Society. 1999, 121 (38): 8728–8740. doi:10.1021/ja990449w.
- ^ Chichak, K. S. Molecular Borromean Rings (PDF). Science. 2004, 304 (5675): 1308–1312 [2021-02-01]. PMID 15166376. doi:10.1126/science.1096914. （原始内容存档 (PDF)于2021-02-24）.
- ^ Tomoe Shimoda, Takeshi Morishima, Koichi Kodama, Takuji Hirose, Dmitry E. Polyansky, Gerald F. Manbeck, James T. Muckerman, Etsuko Fujita. Photocatalytic CO 2 Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO 2 , CO, or Proton. Inorganic Chemistry. 2018-05-07, 57 (9): 5486–5498 [2021-02-02]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.8b00433 （英语）.