3-三丁基錫基吡啶
| 3-三丁基錫基吡啶 | |
|---|---|
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| |
| 識別 | |
| CAS號 | 59020-10-9 
|
| PubChem | 3483848 |
| SMILES |
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| 性質 | |
| 化學式 | C17H31NSn |
| 摩爾質量 | 368.14 g·mol−1 |
| 外觀 | 無色油狀物[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
3-三丁基錫基吡啶是一種有機錫化合物，化學式為C17H31NSn。它可由3-溴吡啶和正丁基鋰（或叔丁基鋰[2]）反應，再與三丁基氯化錫反應製得。[3]它和碘甲烷在乙醚中反應，可以得到1-甲基-3-三丁基錫基吡啶鎓碘化物；和對甲苯磺酸甲酯在乙酸乙酯中反應，可以得到1-甲基-3-三丁基錫基吡啶鎓對甲苯磺酸鹽。[4]
參考文獻
[編輯]- ^ Huifeng Yue; Chen Zhu; Magnus Rueping. Org. Lett. 2018, 20, 2, 385–388. doi:10.1021/acs.orglett.7b03669.
- ^ Nitration of heteroaryltrimethyltins by tetranitromethane and dinitrogen tetroxide: Mechanistic aspects, scope and limitations. European Journal of Organic Chemistry (2003), (9), 1711-1721. doi:10.1002/ejoc.200210611
- ^ Kim, Mi-Kyung; Kim, Yun-Hi; Kwon, Soon-Ki; Chu, Chang-Woong. Antiaromatic compounds and organic light-emitting devices comprising the same. 2015. US20150357578 A1.
- ^ A General Method of Synthesis of Regiospecifically N-Oxidized or N-Quaternized Polyazines by Palladium-Catalyzed Cross-Coupling of N-Oxidized or N-Quaternized Hetaryl Stannanes. Journal of Organic Chemistry (1995), 60 (11), 3487-3493