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環十三烷

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環十三烷
IUPAC名
Cyclotridecane
識別
CAS號 295-02-3  checkY
PubChem 136145
ChemSpider 119922
SMILES
 
  • C1CCCCCCCCCCCC1
InChI
 
  • 1/C13H26/c1-2-4-6-8-10-12-13-11-9-7-5-3-1/h1-13H2
InChIKey UEVXKGPJXXDGCX-UHFFFAOYAD
性質
化學式 C13H26
摩爾質量 182.35 g·mol−1
熔點 23.5 °C(297 K)
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

環十三烷(Cyclotridecane)是13個碳的環烷烴,化學式為。它可以環十二酮氰乙酸乙酯為原料經多步反應製得;[1]它也可以雙環戊酮環己酮三過氧化物為原料反應得到。[2]

參考資料

[編輯]
  1. ^ Matthias K. Diedrich; Frank-Gerrit Klärner. The Effect of Pressure on Cyclizations. The Ring-Size Dependent Reaction Volumes of the Cyclization of 1-Alkenes to Cycloalkanes. Experimental Measurement of Activation and Reaction Volumes of the Intramolecular Diels−Alder Reaction of 1,3,8-Nonatriene and 1,3,9-Decatriene. Temperature Dependence of Activation and Reaction Volumes. J. Am. Chem. Soc. 1998, 120, 25, 6212–6218. doi:10.1021/ja973936p.
  2. ^ Alexandra Seemann; Johannes Panten; Andreas Kirschning. Flow Chemistry under Extreme Conditions: Synthesis of Macrocycles with Musklike Olfactoric Properties. J. Org. Chem. 2021, 86, 20, 13924–13933. doi:10.1021/acs.joc.1c00663