二氫黃樟素
| 二氫黃樟素 | |
|---|---|
| |
| 識別 | |
| CAS號 | 94-58-6 
|
| PubChem | 7197 |
| ChemSpider | 6929 |
| SMILES |
|
| 性質 | |
| 化學式 | C10H12O2 |
| 摩爾質量 | 164.2 g·mol−1 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
二氫黃樟素是一種有機化合物，化學式為C10H12O2。它可由黃樟素或異黃樟素在三氯化釕水合物等催化劑催化下由硼氫化鈉反應得到。[1][2]它在1,4-萘二甲腈存在下於乙腈水溶液中光照反應，可以得到5-丙酰基苯並二噁茂。[3]
參考文獻
[編輯]- ^ Sharma, Pawan K.; Kumar, Surender; Kumar, Pawan; Nielsen, Poul. Selective reduction of mono- and disubstituted olefins by NaBH4 and catalytic RuCl3. Tetrahedron Letters. 2007, 48 (49): 8704–8708. doi:10.1016/j.tetlet.2007.10.017.
- ^ Narisada, Masayuki; Horibe, Isao; Watanabe, Fumihiko; Takeda, Kenichi. Selective reduction of aryl halides and .alpha.,.beta.-unsaturated esters with sodium borohydride-cuprous chloride in methanol and its application to deuterium labeling. The Journal of Organic Chemistry. 1989, 54 (22): 5308–5313. ISSN 0022-3263. doi:10.1021/jo00283a025.
- ^ Pandey, Ganesh; Pal, Sujit; Laha, Ramkrishna. Direct Benzylic C-H Activation for C=O Bond Formation by Photoredox Catalysis. Angewandte Chemie International Edition. 2013-05-03, 52 (19): 5146–5149. ISSN 1433-7851. doi:10.1002/anie.201210333.