4,4'-二苯醚二甲酸铕

4,4'-二苯醚二甲酸铕
识别
CAS号	1392542-49-2（无水） ; 1392483-98-5（五水）
性质
化学式	C42H24Eu2O15
摩尔质量	1072.56 g·mol−1
外观	无色晶体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

4,4'-二苯醚二甲酸铕是一种铕的羧酸盐，化学式为Eu₂(C₁₄H₈O₅)₃，为无色晶体。它的五水合物可由4,4'-二苯醚二甲酸钠和氯化铕于160 °C水热反应得到。^[1]它在紫外光激发下发出红光。^[2]其碱式盐[Eu₅(C₁₄H₈O₅)₇(OH)(H₂O)₂]x·0.5xH₂O是已知的。^[3]

参考文献

^ Renata Łyszczek. Hydrothermal synthesis, thermal and luminescent investigations of lanthanide(III) coordination polymers based on the 4,4′-oxybis(benzoate) ligand. Journal of Thermal Analysis and Calorimetry. 2012-06, 108 (3): 1101–1110 [2020-05-29]. ISSN 1388-6150. doi:10.1007/s10973-011-1987-6 （英语）.
^ Yun Luo, Yanjun Zheng, Guillaume Calvez, Stéphane Freslon, Kevin Bernot, Carole Daiguebonne, Thierry Roisnel, Olivier Guillou. Synthesis, crystal structure and luminescent properties of new lanthanide-containing coordination polymers involving 4,4′-oxy-bis-benzoate as ligand. CrystEngComm. 2013, 15 (4): 706–720 [2020-05-29]. ISSN 1466-8033. doi:10.1039/C2CE26390D （英语）.
^ Yi-Bo Wang, Chang-Yan Sun, Xiang-Jun Zheng, Song Gao, Shao-Zhe Lu, Lin-Pei Jin. Synthesis and characterization of new polynuclear lanthanide coordination polymers with 4,4′-oxybis(benzoic acid). Polyhedron. 2005-05, 24 (7): 823–830 [2020-05-29]. doi:10.1016/j.poly.2005.02.022. （原始内容存档于2020-02-19）（英语）.

[1] Renata Łyszczek. Hydrothermal synthesis, thermal and luminescent investigations of lanthanide(III) coordination polymers based on the 4,4′-oxybis(benzoate) ligand. Journal of Thermal Analysis and Calorimetry. 2012-06, 108 (3): 1101–1110 [2020-05-29]. ISSN 1388-6150. doi:10.1007/s10973-011-1987-6 （英语）.

[2] Yun Luo, Yanjun Zheng, Guillaume Calvez, Stéphane Freslon, Kevin Bernot, Carole Daiguebonne, Thierry Roisnel, Olivier Guillou. Synthesis, crystal structure and luminescent properties of new lanthanide-containing coordination polymers involving 4,4′-oxy-bis-benzoate as ligand. CrystEngComm. 2013, 15 (4): 706–720 [2020-05-29]. ISSN 1466-8033. doi:10.1039/C2CE26390D （英语）.

[3] Yi-Bo Wang, Chang-Yan Sun, Xiang-Jun Zheng, Song Gao, Shao-Zhe Lu, Lin-Pei Jin. Synthesis and characterization of new polynuclear lanthanide coordination polymers with 4,4′-oxybis(benzoic acid). Polyhedron. 2005-05, 24 (7): 823–830 [2020-05-29]. doi:10.1016/j.poly.2005.02.022. （原始内容存档于2020-02-19）（英语）.

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