2,4-戊二胺

2,4-戊二胺
别名	1,3-二甲基-1,3-丙二胺; 2,4-二氨基戊烷
识别
CAS号	591-05-9 ; 29745-96-8（rel-(2R,4S)） ; 29745-97-9（rel-(2R,4R)） ; 34998-98-6（R-(R,R)） ; 34998-99-7（S-(R,R)）
SMILES	NC(C)CC(N)C;
性质
化学式	C5H14N2
摩尔质量	102.18 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

2,4-戊二胺（英語：2,4-pentanediamine）是一种二胺类有机物，化学式为C₅H₁₄N₂。它可由4,5-二氢-3,5-二甲基吡唑在镍催化下加氢反应得到。^[1]它和乙酸酐反应，可以得到N,N'-二乙酰基-2,4-戊二胺。^[2]它和二(4-氧代-1-哌啶基)乙二酮反应，可以得到二(2,4-二甲基-1,5,9-三氮杂螺[5.5]十一烷-9-基)乙二酮。^[3]

参考文献[编辑]

^ Kost, A. N.; Golubeva, G. A.; Stepanov, R. G. Reactions of hydrazine derivatives. XXXIII. Synthesis of 1,3-diamines by hydrogenolysis of pyrazolines. Source Zhurnal Obshchei Khimii, 1962. 32. 2240-2244. ISSN 0044-460X.
^ Shustov, G. V.; Denisenko, S. N.; Chervin, I. I.; Asfandiyarov, N. L.; Kostyanovskii, R. G. Asymmetric nitrogen. 41. Stereochemistry of bicyclic cis-1,2-diaziridines. Tetrahedron, 1985. 41 (23): 5719-5731.
^ Tina Uhlig, Christian Fengler, Andreas Seifert, Florian Taubert, Lysann Kaßner, Hans-Joachim Hähnle, Christoph Hamers, Manfred Wilhelm, Stefan Spange, and Michael Sommer. Reversible and Stable Hemiaminal Hydrogels from Polyvinylamine and Highly Reactive and Selective Bis(N-acylpiperidone)s. ACS Macro Lett. 2021, 10, 3, 389–394. doi:10.1021/acsmacrolett.0c00904.

[1] Kost, A. N.; Golubeva, G. A.; Stepanov, R. G. Reactions of hydrazine derivatives. XXXIII. Synthesis of 1,3-diamines by hydrogenolysis of pyrazolines. Source Zhurnal Obshchei Khimii, 1962. 32. 2240-2244. ISSN 0044-460X.

[2] Shustov, G. V.; Denisenko, S. N.; Chervin, I. I.; Asfandiyarov, N. L.; Kostyanovskii, R. G. Asymmetric nitrogen. 41. Stereochemistry of bicyclic cis-1,2-diaziridines. Tetrahedron, 1985. 41 (23): 5719-5731.

[3] Tina Uhlig, Christian Fengler, Andreas Seifert, Florian Taubert, Lysann Kaßner, Hans-Joachim Hähnle, Christoph Hamers, Manfred Wilhelm, Stefan Spange, and Michael Sommer. Reversible and Stable Hemiaminal Hydrogels from Polyvinylamine and Highly Reactive and Selective Bis(N-acylpiperidone)s. ACS Macro Lett. 2021, 10, 3, 389–394. doi:10.1021/acsmacrolett.0c00904.

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