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1,4-二硫杂环己烷

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1,4-二硫杂环己烷
别名 1,4-二硫六环
识别
CAS号 505-29-3  checkY
性质
化学式 C4H8S2
摩尔质量 120.24 g·mol−1
熔点 110 °C(升华)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

1,4-二硫杂环己烷1,4-二硫六环)是一种有机硫化合物,化学式为C4H8S2,它是二硫杂环己烷英语Dithiane三种同分异构体之一。它可由乙二硫醇1,2-二氯乙烷反应制得。[2]它可以和Ag(I)形成配位聚合物,如{Ag(C4H8S2)X}和{Ag2(C4H8S2)3X2}(X为一价阴离子)。[3]

参考文献

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  1. ^ Gavrilov, B. G.; Tischenko, V. E. Reaction of sodium salts of thiolic acids with saturated α-dibromides. Zhurnal Obshchei Khimii, 1947. 17: 967-974. ISSN 0044-460X.
  2. ^ Brindaban C. Ranu, Ranjan Jana. Ionic Liquid as Catalyst and Reaction Medium: A Simple, Convenient and Green Procedure for the Synthesis of Thioethers, Thioesters and Dithianes using an Inexpensive Ionic Liquid, [pmIm]Br. Advanced Synthesis & Catalysis. 2005-11, 347 (14): 1811–1818 [2022-03-24]. ISSN 1615-4150. doi:10.1002/adsc.200505122. (原始内容存档于2022-03-24) (英语). 
  3. ^ Martin Schröder, Claire Wilson, Simon J. Teat, Peter Hubberstey, John W. Cunningham, Neil R. Champness, Alexander J. Blake, Neil R. Brooks. Anion influence on co-ordination polymers of Ag(I) with 1,4-dithiacyclohexane. Journal of the Chemical Society, Dalton Transactions. 2001-01-01, (17): 2530–2538 [2022-03-24]. ISSN 1364-5447. doi:10.1039/B100635P. (原始内容存档于2022-04-22) (英语).