二溴化(1,5-环辛二烯)铂
外观
二溴化(1,5-环辛二烯)铂 | |
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英文名 | (1,5-Cyclooctadiene)dibromoplatinum |
别名 | 1,5-环辛二烯二溴化铂 |
识别 | |
CAS号 | 12145-48-1 ![]() |
性质 | |
化学式 | C8H12Br2Pt |
摩尔质量 | 463.07 g·mol−1 |
外观 | 浅黄色晶体[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
二溴化(1,5-环辛二烯)铂是一种有机铂化合物,化学式为C8H12Br2Pt。它可由四溴合铂(II)酸钾、乙酸和1,5-环辛二烯在水中加热反应得到,[2]或通过二氯化(1,5-环辛二烯)铂和NiBr2(THF)2在四氢呋喃中反应得到。[1]它可以和碘形成加合物。[3]
参考文献
[编辑]- ^ 1.0 1.1 R. Wyrwa, W. Poppitz, H. Görls. Massenspektrometrische und röntgenstrukturanalytische Untersuchungen an Komplexen des Typs (COD)PtX2 (X = Cl, Br, I, CH3, CH2CMe3, CH2SiMe3). Zeitschrift für anorganische und allgemeine Chemie. 1997, 623 (1-6): 649–653 [2023-03-07]. ISSN 0044-2313. doi:10.1002/zaac.199762301103. (原始内容存档于2023-03-07) (德语).
- ^ M. Belhadj Lachachi, Tayeb Benabdallah, Pedro M. Aguiar, M. Hadj Youcef, Adrian C. Whitwood, Jason M. Lynam. Synthesis of a series of new platinum organometallic complexes derived from bidentate Schiff-base ligands and their catalytic activity in the hydrosilylation and dehydrosilylation of styrene. Dalton Transactions. 2015, 44 (26): 11919–11928 [2023-03-07]. ISSN 1477-9226. doi:10.1039/C5DT01407G (英语).
- ^ Margarita Bulatova, Daniil M. Ivanov, Matti Haukka. Classics Meet Classics: Theoretical and Experimental Studies of Halogen Bonding in Adducts of Platinum(II) 1,5-Cyclooctadiene Halide Complexes with Diiodine, Iodoform, and 1,4-Diiodotetrafluorobenzene. Crystal Growth & Design. 2021-02-03, 21 (2): 974–987 [2023-03-07]. ISSN 1528-7483. doi:10.1021/acs.cgd.0c01314. (原始内容存档于2023-03-07) (英语).